Interfacial dynamics driven by Marangoni stresses on a slowly moving liquid film.

Differential surface tension is a common phenomenon in many chemical and biomedical processes. Localised surface tension gradients due to differential surface loading in thin films give rise to a moving shock front in the direction of higher surface tension. Existence of a background flow enhances the shock wave giving rise to wave breaking and wave separation mechanisms. The effect of a background flow field on Marangoni stress induced shock fronts were investigated in this thesis. Furthermore, a numerical procedure to find approximate solutions to the fully nonlinear flow problem that arises due to Marangoni spreading is proposed. A set of surface evolution equations that incorporates the effects of the background flow field is studied in two major respects: (i) breaking the horizontal symmetry and (ii) nonlinear accretion leading to shock front breaking or separation. The evolution of the surface is evaluated by numerical simulations for a wide range of parameter values. The investigation showed that there are two breaking mechanisms switched by the value of Peclet number. Furthermore it showed that the life time of the shock front is determined by the volumetric flow rate of the film. It is shown here that a weak Marangoni force generates a pure capillary gravity wave that propagates faster than the surfactant front. It is customary to use the lubrication approximations to simplify thin film problems. As a result, the inertial terms in flow equations and nonlinear terms in surface stress balances become excluded. To analyse the fully nonlinear flow, a finite element (FEM) analysis is proposed. The simulations shows that the lubrication theory holds globally in predicting the spreading rates but fails to do so locally until a quasi-steady state is reached. The FEM model shows the formation of two counter-rotating vortices at the beginning which diminish as time evolves. The FEM results are compared with the lubrication theory simulations. FEM model shows rapid film thinning forming extremely thin films within a short period of time. Though detailed transport mechanisms differ, both methods are in close agreement in predicting the spreading rates

Optimised mode selection in electromagnetic sensors for real time, continuous and in-situ monitoring of water cut in multi-phase flow systems

Measurements of the composition of multiphase flows, especially water-cut in oil-water flow, is a frequently encountered problem in the petroleum industry. New techniques that can offer improvements towards that are continuously sought and the use of microwave sensors is considered very promising. The current paper reports on the performance of a microwave cylindrical resonator, integrated into a multiphase flow experimental facility, used to determine water-cut in an upward flowing oil-water mixture. The performance and suitability of two microwave resonant modes (TM010 and TM110) was studied. The TM110 mode was found to be less dependent on the spatial phase distribution of the oil-water flowing mixture and provided more consistent results across a broader flow regime. The relative errors between the predicted and actual water-cut were from −6.53% to 9.16% and relative errors of 78% of the total data points were inside −5% to 5%. The results suggest that appropriate sensor design and careful selection of the operating frequency/resonant pattern can offer a powerful technique for real time, on-line and non-destructive determination of water-cut in multiphase flow systems

Gas rising through a large diameter column of very viscous liquid: Flow patterns and their dynamic characteristics

Gas-liquid flows are affected strongly by both the liquid and gas properties and the pipe diameter, which control features and the stability of flow patterns and their transitions. For this reason, empirical models describing the flow dynamics can be applied only to limited range of conditions. Experiments were carried out to study the behaviour of air passing through silicone oil (360 Pa.s) in 240 mm diameter bubble column using Electrical Capacitance Tomography and pressure transducers mounted on the wall. These experiments are aimed at reproducing expected conditions for flows including (but not limited to) crude oils, bitumen, and magmatic flows in volcanic conduits. The paper presents observation and quantification of the flow patterns present. It particularly provides the characteristics of gas-liquid slug flows such as: void fraction; Taylor bubble velocity; frequency of periodic structures; lengths of liquid slugs and Taylor bubbles. An additional flow pattern, churn flow, has been identified. The transition between slug and churn has been quantified and the mechanism causing it are elucidated with the assistance of a model for the draining of the liquid film surrounding the Taylor bubble once this has burst through the top surface of the aerated column of gas-liquid mixture. It is noted that the transition from slug to churn is gradual

On the design and simulation of an airlift loop bioreactor with microbubble generation by fluidic oscillation

Microbubble generation by a novel fluidic oscillator driven approach is analyzed, with a view to identifying the key design elements and their differences from standard approaches to airlift loop bioreactor design. The microbubble generation mechanism has been shown to achieve high mass transfer rates by the decrease of the bubble diameter, by hydrodynamic stabilization that avoids coalescence increasing the bubble diameter, and by longer residence times offsetting slower convection. The fluidic oscillator approach also decreases the friction losses in pipe networks and in nozzles/diffusers due to boundary layer disruption, so there is actually an energetic consumption savings in using this approach over steady flow. These dual advantages make the microbubble generation approach a promising component of a novel airlift loop bioreactor whose design is presented here. The equipment, control system for flow and temperature, and the optimization of the nozzle bank for the gas distribution system are presented. (C) 2009 The Institution of Chemical Engineers. Published by Elsevier B.V All rights reserved

Experimental investigation of helicity in turbulent swirling jet using dual-plane dye laser PIV technique

This paper reports a new method of generating two light sheets using a dye laser system and the use of this dual-plane dye laser system to analyse average helicity and energy dissipation in a turbulent swirling flow. The dual-plane PIV system that was used in this study consisted of three cameras and a single frequency Nd:YAG laser, which was used to generate two parallel light sheet planes with differing wavelengths(colour). The method of generating two different light sheet wavelengths using a single laser source is an innovative and new technique. Stereoscopic PIV measurements were obtained in one plane with the use of two CCD cameras, and standard PIV measurements were obtained in the other plane with the use of one CCD camera. The light scattered by the particles on two different light sheets were separated using appropriate optical filters. The measurements obtained were used to estimate the components of the velocity gradient tensor. The tensor components were then used to determine the average vorticity components and helicity quantities of the fluid that was investigated. To determine the average turbulent kinetic energy dissipation, the continuity equation was used to infer the out-of-plane gradient of the out-of-plane velocity. From the analysis of the results, it was found that regions with high helicity were correlated with regions of high turbulent kinetic energy dissipation. © 2008 Springer-Verlag

The pairwise interaction of coalescing air bubbles in water

There is a relative scarcity of experimental data relating to the interaction of a pair of millimetre-scale air bubbles rising having an offset configuration through stagnant water. To add to this dataset was the motivation behind this work. A series of experiments are presented, which can add to the understanding of bubble-bubble interaction. The trajectories of bubble pairs were tracked using a high speed camera. The diameter and relative positions of the nozzles were varied to produce different separation distances between the rising bubbles. It was found that when the trailing bubble is slightly smaller (as little as 2.3%) than the leading bubble it would approach the leading bubble. Hence, a greater tendency to coalesce between the rising pairs has been noticed. The initial relative angle between the coalesced bubbles, , was also correlated which has agreed well with others’ previous work. A proportional relationship has been presented to link the time required for coalescence with the ratio of the bubbles radii. A complementary set of numerical simulations, using a multiphase CFD model with adaptive meshing, have confirmed some of the experimental observations and added insights into the flow structures responsible for coalescence. Finally, a map for the boundaries of coalescence from the numerical and experimental observations is suggested which relates the separation of the bubbles and their radii ratio to the likelihood of coalescence

Fluid structure behaviour in gas-oil two-phase flow in a moderately large diameter vertical pipe

Intermittent flows in vertical pipes occur in many industrial settings including power generation and downstream oil-and gas production. This type of flows include cap bubble, slug and churn flow regimes. These regimes are of interest as downstream processes and control may heavily depend on the intermittency of the inflow. There are a number of correlations that predicts the features in such flows in vertical pipes. Most of the correlations were developed for air and water fluid pair for slug flow regime in vertical pipes with 25 to 50 mm inner diameter. In this paper, an attempt has been made to assess the suitability of several of these correlations specific to slug flow regime for a fluid pair that is different to air-water system. In this work, air-silicone oil flow development was experimentally investigated in a vertical pipe with an inner diameter of 68mm. A Wire Mesh Sensor (WMS) and an Electrical Capacitance Tomography (ECT) sensor were installed in series at four locations (15D, 30D, 45D and 65D) downstream of the mixing section. The flow was visually observed using a high speed camera. The void fraction time series obtained from the WMS and the ECT were used to establish the flow characteristics such as slug length, slug frequency, void fraction in liquid slugs and Taylor bubble velocity. A comparison showed that the void fraction measurements using ECT and WMS are in good agreement. Axial measurements shows that the flow development beyond 45D is minimal. Change in physical properties of the liquid phase is responsible for the deviation associated with the existing slug flow models, particularly those developed to predict the gas holdup in liquid slugs

Cellulosic-crystals as a fumed-silica substitute in vacuum insulated panel technology used in building construction and retrofit applications

This article investigates impact of substituting fumed silica with a cellulosic-crystal innovation in a commercial Vacuum Insulated Panel (VIP) core. High building performance demands have attracted VIP technology investment to increase production capacity and reduce cost. In building retrofit VIPs resolve practical problems on space saving that conventional insulations are unsuitable for. Three challenges exists in fumed silica: cost, low sustainability properties, and manufacture technical maturity. Cellulosic nano-crystal (CNC) technology is in its infancy and was identified as a possible alternative due to a similar physical nano-structure, and biodegradability. The study aim was to determine a performance starting point and establish how this compares with the current benchmarks. Laboratory cellulosic-crystal samples were produced and supplied for incorporation into commercial VIP manufacture. A selection of cellulosic-panels with core densities ranging 127–170 kg/m3 were produced. Thermal conductivities were tested at a pressure of 1 Pa (0.01 mBar), with the results compared against a selection of fumed silica-VIPs with core densities ranging 144–180 kg/m3. Conductivity tests were then done on a cellulosic-VIP with 140 kg/m3 density, under variable pressures ranging 1–100,000 Pa (0.01–1000 mBar). This investigated panel lifespan performance, with comparisons made to a fumed silica-VIP of similar core density. Manufactured cellulosic-samples were found unsuitable as a commercial substitute, with performance below current standards. Areas for cellulosic nano-material technology development were identified that show large scope for improvement. Pursuit could create a new generation of insulation materials that resolve problems associated with current commercial versions. This is most applicable in building retrofit where large ranges of domestic and commercial cases are marginalised from their construction markets due to impracticalities and high upgrade costs. This being a problem in multiple economies globally

New Algorithm to Discriminate Phase Distribution of Gas-Oil-Water Pipe Flow With Dual-Modality Wire-Mesh Sensor

Three-phase gas-oil-water flow is an important type of flow present in petroleum extraction and processing. This paper reports a novel threshold-based method to visualize and estimate the cross-sectional phase fraction of gas-oil-water mixtures. A 16×16 dual-modality wire-mesh sensor (WMS) was employed to simultaneously determine the conductive and capacitive components of the impedance of fluid. Then, both electrical parameters are used to classify readings of WMS into either pure substance (gas, oil or water) or two-phase oil-water mixtures (foam is neglected in this work). Since the wire-mesh sensor interrogates small regions of the flow domain, we assume that the three-phase mixture can be segmented according to the spatial sensor resolution (typically 2–3 mm). Hence, the proposed method simplifies a complex three-phase system in several segments of single or two-phase mixtures. In addition to flow visualization, the novel approach can also be applied to estimate quantitative volume fractions of flowing gas-oil-water mixtures. The proposed method was tested in a horizontal air-oil-water flow loop in different flow conditions. Experimental results suggest that the threshold-based method is able to capture transient three-phase flows with high temporal and spatial resolution even in the presence of water-oil dispersion regardless of the continuous phase

A study of droplet impact on static films using the BB-LIF technique

This paper presents results of single droplet impacts on films of different height taken using the Brightness Based Laser Induced Fluorescence technique (BB-LIF). The dynamics of drop impingement such as the shape of the cavity, residual film thickness are investigated and analysed with a time-resolution of 0.1 ms and spatial resolution of 70 um. Additionally a variation of the BB-LIF technique is used to investigate the change in profile of the droplet liquid during the inertial self-similar regime. The results of the analysis show that present models predicting initial development of the cavity show good agreement. Suggested amendments for some of the constants for cavity width and residual film thickness are proposed based on the film thickness, that fit better with published data. The development of the profile of the droplet liquid demonstrates that for thin liquid films, the droplet liquid behavior with strong similarity to droplet impact on dry solid surfaces. It is noted that for some of the measured parameters, the use of the film height as the lengthscale gives a better fit